- Meixiang Wang, Pengyao Zhang, Mohammad Shamsi, Jacob L. Thelen, Wen Qian, Vi Khanh Truong, Jinwoo Ma, Jian Hu, Michael D. Dickey. Tough and stretchable ionogels by in situ phase separation. Nature Materials, 2022; DOI: 10.1038/s41563-022-01195-4
“Materials that can be deformed, but that are difficult to break or tear, are desirable,” says Michael Dickey, co-corresponding author of a paper on the work and the Camille & Henry Dreyfus Professor of Chemical and Biomolecular Engineering at North Carolina State University. “Nature is good at this; think of cartilage as an example. But engineering synthetic materials with these properties has been difficult, which makes our work here exciting.”
The new materials fall under the broader category of ionogels, which are polymer networks that contain salts that are liquid at room temperature. These salts are called ionic liquids.
Dickey and his collaborators have made ionogels that are nearly 70% liquid, but have remarkable mechanical properties. Namely, they’re tough — meaning they can dissipate a lot of energy when you deform them, making them very difficult to break. They’re also easy to make, easy to process, and you can 3D print them.
“Hydrogels, which are polymer networks that contain water, are fairly common,” Dickey says. “For example, contact lenses are hydrogels. But ionogels have some advantages over hydrogels. Ionic liquids don’t evaporate like water, so you don’t have to worry about the ionogels drying out. Ionogels are also electrically and thermally stable and conduct electricity well, raising some interesting opportunities for future applications.”
To make the new ionogels, the researchers started with monomers of polyacrylic acid (used in baby diapers) and polyacrylamide (used in contact lenses) and copolymerized them in a solution of ionic liquid using ultraviolet light. In other words, they took the ingredients for polyacrylic acid and polyacrylamide, placed them in an ionic liquid, and shone light on it to create a copolymer that incorporates both monomers and the ionic liquid itself.
“The end result is significantly better than an average of the two materials,” Dickey says. “It is like adding 1+1 and getting 10. The resulting gel has the stretchability of polyacrylic acid and is even stronger than the polyacrylamide. In terms of toughness, it’s better than cartilage. But the differences between ionogels and hydrogels make them advantageous for different applications.”
In addition, the ionogels created by Dickey’s team also have self-healing and shape memory properties. You can stick two pieces of the ionogel together, expose it to heat, and it reforms a strong bond. By the same token, you can deform the ionogel into a temporary new shape, but it will return to its original shape when exposed to heat. The amount of heat needed depends on how quickly you want the material to “heal” or return to its normal shape. When exposed to a temperature of 60 degrees Celsius, the actions only take tens of seconds.
“We’re excited that we’ve made something with truly remarkable properties that can be made very easily — you just shine light on it — using widely available polymers,” Dickey says. “And you can tailor the properties of the ionogels by controlling the ratio of ingredients during the copolymerization process.
“We’re already working with one industry partner, and are open to working with others to develop applications for this new breed of ionogels.”
Video of the ionogels: https://youtu.be/SoAxmv7I9KA
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New material offers remarkable combo of toughness and stretchiness